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    One-electron reduction of 5-deazalumiflavin in aqueous solution: a pulse radiolysis study.

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    Authors
    Heelis, P F
    Parsons, B J
    Phillips, G O
    Swallow, A John
    Affiliation
    Research Division, North East Wales Institute, Deeside, Clwyd, U.K.
    Issue Date
    1989-04
    
    Metadata
    Show full item record
    Abstract
    The one-electron reduction of 5-deazalumiflavin has been studied in aqueous solution in the acidity range H0 = -1 to pH 13 using the reducing species CO2-, e-aq and (CH3)2COH radicals. The spectral and other properties of the deazaflavin radicals formed were found to be independent of the reductant used. Four protolytic forms of the radical were distinguished with associated pKa values of 1.3 +/- 0.3, 6.0 +/- 0.3 and 10.7 +/- 0.3.
    Citation
    One-electron reduction of 5-deazalumiflavin in aqueous solution: a pulse radiolysis study. 1989, 55 (4):557-62 Int. J. Radiat. Biol.
    Journal
    International Journal of Radiation Biology
    URI
    http://hdl.handle.net/10541/111007
    DOI
    10.1080/09553008914550601
    PubMed ID
    2564866
    Type
    Article
    Language
    en
    ISSN
    0955-3002
    ae974a485f413a2113503eed53cd6c53
    10.1080/09553008914550601
    Scopus Count
    Collections
    All Paterson Institute for Cancer Research

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