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    One-electron reduction of 8-hydroxy-5-deazaisoalloxazine in aqueous solution: a pulse radiolysis study.

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    Authors
    Heelis, P F
    Parsons, B J
    Swallow, A John
    Affiliation
    North East Wales Institute, Deeside, Clwyd, UK.
    Issue Date
    1991-03
    
    Metadata
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    Abstract
    The one-electron reduction of 8-hydroxy-5-deazaisoalloxazine (HMDI) has been studied in aqueous solution in the acidity range pH 0 to 13 using the reducing species CO2.-, eaq- and (CH3)2COH radicals. The spectral and other properties of the HMDI radicals were found to be independent of the reductant used. Four protolytic forms of the radical were distinguished with associated pKa values of 2.3 +/- 0.3, 6.0 +/- 0.3 and 10.1 +/- 0.3.
    Citation
    One-electron reduction of 8-hydroxy-5-deazaisoalloxazine in aqueous solution: a pulse radiolysis study. 1991, 59 (3):611-6 Int. J. Radiat. Biol.
    Journal
    International Journal of Radiation Biology
    URI
    http://hdl.handle.net/10541/104726
    DOI
    10.1080/09553009114550541
    PubMed ID
    1672351
    Type
    Article
    Language
    en
    ISSN
    0955-3002
    ae974a485f413a2113503eed53cd6c53
    10.1080/09553009114550541
    Scopus Count
    Collections
    All Paterson Institute for Cancer Research

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