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C-H Borylation: no need to stop for directions

Osborne, Hugh C
Durie, A.
Schmidt, Christine K
Larrosa, I.
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Abstract
A recent work by Hartwig et al. details an efficient method to borylate strong primary C(sp3)–H bonds via iridium-catalysed C–H activation. The conditions confer counterintuitive selectivity over more labile C–H bonds, while providing an avenue for a gamut of synthetically valuable late-stage functionalisations through versatile borylate intermediates.
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2020
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Article
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Osborne HC, Durie A, Schmidt CK, Larrosa I. C–H Borylation: No Need to Stop for Directions. Trends in Chemistry. 2020;2(11):957-9.
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